Skip to Main Content

Boatwright Memorial Library

Spring 2025 Chemistry Presentations

Under each presentation: 

you will find any selected resources as listed on https://blog.richmond.edu/chemseminar/ with links to the resource in the library's OneSearch if available.

Under some of the presentations: 

you will find related resources curated by the science librarian. These resources might be broad overviews of topics or they might be specific. They are meant to serve as a starting point. 

Want to just see all the resources at once? Check out the Zotero Folder for Chemistry Seminar Presentations. 

*Zotero Folder reflects updates quickest*

Iron-Catalyzed Reactions of Ketones: From Amination to Cycloaromatization

- Professor Alexandra StromJanuary 17, 2025 ▼

  1. Song, F.; Park, S. H.; Wu, C.; Strom, A. E. Iron-Catalyzed Oxidative α-Amination of Ketones with Primary and Secondary Sulfonamides. J. Org. Chem. 2023, 88 (5), 3353–3358. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9990065.
  2. Parrales, G. M.; Hollin, N. C.; Song, F.; Lyu, Y.; Martin, A.-M. O.; Strom, A. E. Mechanism of Iron-Catalyzed Oxidative α-Amination of Ketones with Sulfonamides. J. Org. Chem. 2024, 89 (17), 12462–12466. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_11382155.

  1. McGeough, C. P.; Strom, A. E.; Jamison, T. F. Ni-Catalyzed Cross-Electrophile Coupling for the Synthesis of Skipped Polyenes. Org. Lett. 2019, 21 (10), 3606–3609. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6681449.
  2. Alexandra Strom. Smith College. https://www.smith.edu/people/alexandra-strom (accessed 2024-12-09).

The history of chemical information: Helping history and chemistry help each other

- Professor Evan Hepler-SmithFebruary 7, 2025 ▼

  1. Hepler-Smith, E. “Just as the Structural Formula Does”: Names, Diagrams, and the Structure of Organic Chemistry at the 1892 Geneva Nomenclature Congress. Ambix 2015, 62 (1), 1–28. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1179_1745823414Y_0000000006.
  2. Hepler-Smith, E. Systematic Flexibility and the History of the IUPAC Nomenclature of Organic Chemistry. Chemistry International 2015, 37 (2), 10–14. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1515_ci_2015_0232.
  3. Hepler-Smith, E. “A Way of Thinking Backwards” Computing and Method in Synthetic Organic Chemistry. Historical Studies in the Natural Sciences 2018, 48 (3), 300–337. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_journals_2104172143.
  4. Hepler-Smith, E. Paper Chemistry: François Dagognet and the Chemical Graph. Ambix 2018, 65 (1), 76–98. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_1989575881.
  5. Hepler-Smith, E. Molecular Bureaucracy: Toxicological Information and Environmental Protection. Environmental History 2019, 24 (3), 534–560. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_uchicagopress_journals_emy134.
  6. Hepler-Smith, E.; McEwen, L. A Century of Nomenclature for Chemists and Machines. Chemistry International 2019, 41 (3), 46–49. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1515_ci_2019_0315.

  1. Browne, C. A.; Weeks, M. elvira. A History of the American Chemical Society, Seventy-Five Eventful Years; American Chemical Society: Washington, 1952. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/191gg5k/alma991515633606241
  2. Chang, H. Inventing Temperature: Measurement and Scientific Progress; Oxford Studies in Philosophy of Science Ser; Oxford University Press, Incorporated: New York, 2004. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_36950529 
  3. Crane, E. J.; Patterson, A. M.; Marr, E. B. A Guide to the Literature of Chemistry, 2nd ed.; John Wiley & Sons, Inc: New York, 1957. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_hathitrust_hathifiles_wu_89046373171  
  4. Grossman, J. R. Everything Has a History. Perspectives on History. December 1, 2015. https://www.historians.org/perspectives-article/everything-has-a-history-december-2015/. 
  5. Grubesic, T. H.; Matisziw, T. C. On the Use of ZIP Codes and ZIP Code Tabulation Areas (ZCTAs) for the Spatial Analysis of Epidemiological Data. Int J Health Geogr 2006, 5 (1). https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_doaj_primary_oai_doaj_org_article_570fb3379ef24e6e9241fe97be6f95c6. 
  6. Hoffmann, R. Roald Hoffmann on the Philosophy, Art, and Science of Chemistry; Kovac, J., Weisberg, M., Eds.; Oxford scholarship online; Oxford University Press: New York, 2020. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/191gg5k/alma9913572043606241. 
  7. Kim, S.; Bucholtz, E. C.; Briney, K.; Cornell, A. P.; Cuadros, J.; Fulfer, K. D.; Gupta, T.; Hepler-Smith, E.; Johnston, D. H.; Lang, A. S. I. D.; Larsen, D.; Li, Y.; McEwen, L. R.; Morsch, L. A.; Muzyka, J. L.; Belford, R. E. Teaching Cheminformatics through a Collaborative Intercollegiate Online Chemistry Course (OLCC). J. Chem. Educ. 2021, 98 (2), 416–425. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_7976600. 
  8. Lykknes, A.; Van Tiggelen, B. Women in Their Element: Selected Women’s Contributions to the Periodic System; World scientific: Singapore New Jersey London, 2019. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/191gg5k/alma9926834273606241 
  9. Papadópoulos, D.; Puig de La Bellacasa, M.; Myers, N. Reactivating Elements: Chemistry, Ecology, Practice; Elements; Duke University Press: Durham (N.C.), 2021. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/191gg5k/alma9928236478606241 
  10. Calvin N. Mooers papers. University of Minnesota Libraries. 1947. https://archives.lib.umn.edu/repositories/3/resources/105. 
  11. Sylvester, J. J. History of the Plagiograph. Nature 1875, 12 (298), 214–216.https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1038_012214b0  
  12. Trouillot, M.-R. Silencing the Past: Power and the Production of History; Beacon Press: Boston (Mass.), 1995. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/191gg5k/alma993836483606241 
  13. Williams, R. V. Madeline M. Henderson: From Chemical Information Science Pioneer to Architect of the New Information Science. Libraries and the Cultural Record 2010, 45 (2), 167–184. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_742894005
  14. Everything Is Chemistry Brussels Sprout. https://www.whatsinsidescjohnson.com/-/media/images/downloadpdfs/pdf/scjohnson_everything_is_chemistry-brussels-sprout.pdf.
  15. Conference on Mechanical Processing of Chemical Information, March 5-8, 1964, Airlie House, Warrenton, Virginia; The National Academies Press: Washington, DC, 1964. https://nap.nationalacademies.org/catalog/20819/conference-on-mechanical-processing-of-chemical-information-march-5-8-1964-airlie-house-warrenton-virginia.
  16. Evan Hepler-Smith |Department of History. Duke University. https://history.duke.edu/evan-hepler-smith.

Electron-rich aniline as cleavable linkers for peptides

- Andrew Watts (Student Speaker)February 14, 2025 ▼

  1. Taggart, E. L.; Wolff, E. J.; Yanar, P.; Blobe, J. P.; Shugrue, C. R. Development of an Oxazole-Based Cleavable Linker for Peptides. Bioorganic & Medicinal Chemistry 2024, 102, 117663. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2954776030.
  2. Watts, A. M.; Hughes, C. J.; Clausen, G. A.; Yanar, P.; Wolff, E. J.; Rubio, P. R.; Stuart, N. M.; Shugrue, C. R. Electron-Rich Anilines as Cleavable Linkers for Peptides. Bioorganic Chemistry 2025, 154, 108084. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_3151454667.

  1. Rössler, S. L.; Grob, N. M.; Buchwald, S. L.; Pentelute, B. L. Abiotic Peptides as Carriers of Information for the Encoding of Small-Molecule Library Synthesis. Science 2023, 379 (6635), 939–945. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2783498263.
  2. Rossino, G.; Marchese, E.; Galli, G.; Verde, F.; Finizio, M.; Serra, M.; Linciano, P.; Collina, S. Peptides as Therapeutic Agents: Challenges and Opportunities in the Green Transition Era. Molecules 2023, 28 (20), 7165. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_doaj_primary_oai_doaj_org_article_69202c2a329546f7aaa829e4174d2326.
  3. Leriche, G.; Chisholm, L.; Wagner, A. Cleavable Linkers in Chemical Biology. Bioorganic & Medicinal Chemistry 2012, 20 (2), 571–582. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_923202664.

CO2 Reduction to Methanol via Organocatalysts

- Nehal Asif (Student Speaker)February 21, 2025 ▼

  1. Maki, T.; Ishihara, K.; Yamamoto, H. 4,5,6,7-Tetrachlorobenzo[d][1,3,2]Dioxaborol- 2-Ol as an Effective Catalyst for the Amide Condensation of Sterically Demanding Carboxylic Acids. Org. Lett. 2006, 8 (7), 1431–1434. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_67804786.
  2. Mohler, L. K.; Czarnik, A. W. α-Amino Acid Chelative Complexation by an Arylboronic Acid. J. Am. Chem. Soc. 1993, 115 (15), 7037–7038. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pascalfrancis_primary_4890435.
  3. Schleyer, P. von R.; Jiao, H.; Hommes, N. J. R. van E.; Malkin, V. G.; Malkina, O. L. An Evaluation of the Aromaticity of Inorganic Rings:  Refined Evidence from Magnetic Properties. J. Am. Chem. Soc. 1997, 119 (51), 12669–12670. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1021_ja9719135.
  4. Thilagar, P.; Chen, J.; Lalancette, R. A.; Jäkle, F. Reversible Formation of a Planar Chiral Ferrocenylboroxine and Its Supramolecular Structure. Organometallics 2011, 30 (24), 6734–6741. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1021_om200947v.

  1. Cao, K.-S.; Bian, H.-X.; Zheng, W.-H. Mild Arylboronic Acid Catalyzed Selective [4 + 3] Cycloadditions: Access to Cyclohepta[b]Benzofurans and Cyclohepta[b]Indoles. Org. Biomol. Chem. 2015, 13 (23), 6449–6452. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_1686068550.
  2. Ching, H. Y. V.; Wang, X.; He, M.; Perujo Holland, N.; Guillot, R.; Slim, C.; Griveau, S.; Bertrand, H. C.; Policar, C.; Bedioui, F.; Fontecave, M. Rhenium Complexes Based on 2-Pyridyl-1,2,3-Triazole Ligands: A New Class of CO2 Reduction Catalysts. Inorg. Chem. 2017, 56 (5), 2966–2976. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_hal_primary_oai_HAL_hal_03919371v1.
  3. Houston, T. A.; Wilkinson, B. L.; Blanchfield, J. T. Boric Acid Catalyzed Chemoselective Esterification of α-Hydroxycarboxylic Acids. Org. Lett. 2004, 6 (5), 679–681. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_71684271.
  4. Yang, W.; Gao, X.; Wang, B. Boronic Acid Compounds as Potential Pharmaceutical Agents. Medicinal Research Reviews 2003, 23 (3), 346–368. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_73122993.

Ring-Enlargement of in Situ Generated Cyclopropanones by the Reaction with Sulfonium Ylides: One-Pot Synthesis of Cyclobutanones

- Louisa Fiertz (Student Speaker)February 21, 2025 ▼

  1. Chigboh, K.; Morton, D.; Nadin, A.; Stockman, R. A. Synthesis of Chiral Non-Racemic Substituted Vinyl Aziridines. Tetrahedron Letters 2008, 49 (32), 4768–4770. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1016_j_tetlet_2008_05_090.
  2. Lange, M.; Werz, D. B. Ring-Enlargement of in Situ Generated Cyclopropanones by the Reaction with Sulfonium Ylides: One-Pot Synthesis of Cyclobutanones. Org. Lett. 2024, 26 (46), 9871–9876. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_3154244705.
  3. Poteat, C. M.; Jang, Y.; Jung, M.; Johnson, J. D.; Williams, R. G.; Lindsay, V. N. G. Enantioselective Synthesis of Cyclopropanone Equivalents and Application to the Formation of Chiral β-Lactams. Angewandte Chemie International Edition 2020, 59 (42), 18655–18661. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2421122823.
  4. Poteat, C. M.; Lindsay, V. N. G. Stereospecific Synthesis of Enantioenriched Alkylidenecyclobutanones via Formal Vinylidene Insertion into Cyclopropanone Equivalents. Org. Lett. 2021, 23 (16), 6482–6487. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2559664301.

Spatially resolved mechanistic studies at electrode–electrolyte and gas–liquid interfaces

- Professor Megan JacksonFebruary 28, 2025 ▼

  1. Chua, K. O.; Jackson, M. N. Step Edge Defects Have Nanoscale Impact on the Electronic Structure in Semiconducting Transition Metal Dichalcogenide Electrocatalysts. J. Am. Chem. Soc. 2025, 147 (5), 4643–4653. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_3160460660.

  1. Bollinger, M. V.; Lauritsen, J. V.; Jacobsen, K. W.; Nørskov, J. K.; Helveg, S.; Besenbacher, F. One-Dimensional Metallic Edge States in MoS2. Phys. Rev. Lett. 2001, 87 (19), 196803. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_72252973.
  2. Collins, N. Water droplets spontaneously produce hydrogen peroxide. Stanford Report. https://news.stanford.edu/stories/2019/08/water-droplets-spontaneously-produce-hydrogen-peroxide (accessed 2025-03-05).
  3. Daviddi, E.; Gonos, K. L.; Colburn, A. W.; Bentley, C. L.; Unwin, P. R. Scanning Electrochemical Cell Microscopy (SECCM) Chronopotentiometry: Development and Applications in Electroanalysis and Electrocatalysis. Anal. Chem. 2019, 91 (14), 9229–9237. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2250629210.
  4. Dempsey, J. L.; Jackson, M. N.; Peroff, A. G. Meeting the Need: Formal Electrochemistry Training through Workshops. J. Chem. Educ. 2024, 101 (2), 483–489. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1021_acs_jchemed_3c00875.
  5. Eatoo, M. A.; Mishra, H. Busting the Myth of Spontaneous Formation of H2O2 at the Air–Water Interface: Contributions of the Liquid–Solid Interface and Dissolved Oxygen Exposed. Chem. Sci. 2024, 15 (9), 3093–3103. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10901496.
  6. Fan, X.-L.; Yang, Y.; Xiao, P.; Lau, W.-M. Site-Specific Catalytic Activity in Exfoliated MoS2 Single-Layer Polytypes for Hydrogen Evolution: Basal Plane and Edges. J. Mater. Chem. A 2014, 2 (48), 20545–20551. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_rsc_primary_c4ta05257a.
  7. Gallo Jr, A.; Musskopf, N. H.; Liu, X.; Yang, Z.; Petry, J.; Zhang, P.; Thoroddsen, S.; Im, H.; Mishra, H. On the Formation of Hydrogen Peroxide in Water Microdroplets. Chem. Sci. 2022, 13 (9), 2574–2583. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_journals_2637137708.
  8. Hao, H.; Leven, I.; Head-Gordon, T. Can Electric Fields Drive Chemistry for an Aqueous Microdroplet? Nat Commun 2022, 13 (1), 280. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_doaj_primary_oai_doaj_org_article_02dbdcad23c748d3baaafa3950fc7b5d.
  9. Hilmer, J. Electrospray Ionization; 2009. https://en.wikipedia.org/wiki/File:Electrospray_ionization.jpg.
  10. Jackson, M. N.; Surendranath, Y. Donor-Dependent Kinetics of Interfacial Proton-Coupled Electron Transfer. J. Am. Chem. Soc. 2016, 138 (9), 3228–3234. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_1772147535.
  11. Jaramillo, T. F.; Jørgensen, K. P.; Bonde, J.; Nielsen, J. H.; Horch, S.; Chorkendorff, I. Identification of Active Edge Sites for Electrochemical H2 Evolution from MoS2 Nanocatalysts. Science 2007, 317 (5834), 100–102. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1126_science_1141483.
  12. Leimkuhl, D. P.; Donley, C. L.; Jackson, M. N. Controlling Nucleation Sites for Metal Oxide Film Growth on Glassy Carbon via Electrochemical Preoxidation. ACS Appl. Mater. Interfaces 2024, 16 (2), 2868–2876. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2915990034.
  13. McGlynn, J. C.; Cascallana-Matías, I.; Fraser, J. P.; Roger, I.; McAllister, J.; Miras, H. N.; Symes, M. D.; Ganin, A. Y. Molybdenum Ditelluride Rendered into an Efficient and Stable Electrocatalyst for the Hydrogen Evolution Reaction by Polymorphic Control. Energy Technology 2018, 6 (2), 345–350. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_journals_1999464128.
  14. McGlynn, J. C.; Dankwort, T.; Kienle, L.; Bandeira, N. A. G.; Fraser, J. P.; Gibson, E. K.; Cascallana-Matías, I.; Kamarás, K.; Symes, M. D.; Miras, H. N.; Ganin, A. Y. The Rapid Electrochemical Activation of MoTe2 for the Hydrogen Evolution Reaction. Nat Commun 2019, 10 (1), 4916. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_doaj_primary_oai_doaj_org_article_fa2ace573bb048ab9cc5470767901bbf.
  15. Montgomery, C. L.; Lee, J.; Donley, C. L.; Jackson, M. N.; Tereniak, S. J.; Dempsey, J. L. Kinetic Analysis of Proton-Coupled Electron Transfer at an Electrode-Immobilized Complex. ACS Electrochem. 2024. https://doi.org/10.1021/acselectrochem.4c00099.
  16. NASA Science Editorial Team. Aerosols: Small Particles with Big Climate Effects. NASA Science. https://science.nasa.gov/science-research/earth-science/climate-science/aerosols-small-particles-with-big-climate-effects/ (accessed 2025-03-05).
  17. The Materials Project. Materials Data on MoS2, 2020. https://next-gen.materialsproject.org/materials/mp-2815#how_to_cite.
  18. The Materials Project. Materials Data on Te2Mo, 2020. https://next-gen.materialsproject.org/materials/mp-7459.
  19. Trager, R. Water microdroplet chemistry is contentious, here’s why. Chemistry World. https://www.chemistryworld.com/news/water-microdroplet-chemistry-is-contentious-heres-why/4018721.article (accessed 2025-03-05).
  20. Uliana, A. A.; Pezoulas, E. R.; Zakaria, N. I.; Johnson, A. S.; Smith, A.; Lu, Y.; Shaidu, Y.; Velasquez, E. O.; Jackson, M. N.; Blum, M.; Neaton, J. B.; Yano, J.; Long, J. R. Removal of Chromium and Arsenic from Water Using Polyol-Functionalized Porous Aromatic Frameworks. J. Am. Chem. Soc. 2024, 146 (34), 23831–23841. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_unpaywall_primary_10_1021_jacs_4c05728.
  21. Xie, J.; Zhang, H.; Li, S.; Wang, R.; Sun, X.; Zhou, M.; Zhou, J.; Lou, X. W. (David); Xie, Y. Defect-Rich MoS2 Ultrathin Nanosheets with Additional Active Edge Sites for Enhanced Electrocatalytic Hydrogen Evolution. Advanced Materials 2013, 25 (40), 5807–5813. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1002_adma_201302685.
  22. Advanced aerosol delivery devices and services. Philips. https://www.usa.philips.com/healthcare/resources/landing/rdd-pharmaceuticals-enhanced-drug-delivery (accessed 2025-03-05).
  23. Lab Page Home. The Jackson Lab. https://squarescheme.squarespace.com (accessed 2024-12-09).
  24. Jackson, Megan – Department of Chemistry. University of North Carolina. https://chem.unc.edu/faculty/jackson-megan/ (accessed 2024-12-09).

Disordered yet specific: small-molecule binding to the intrinsically disordered protein c-Myc

- Professor Steven MetalloMarch 7, 2025 ▼

  1. Dobrev, V. S.; Fred, L. M.; Gerhart, K. P.; Metallo, S. J. Chapter Twenty-One - Characterization of the Binding of Small Molecules to Intrinsically Disordered Proteins. In Methods in Enzymology; Rhoades, E., Ed.; Intrinsically Disordered Proteins; Academic Press, 2018; Vol. 611, pp 677–702. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_ebookcentralchapters_5603746_596_698.
  2. Jaiprashad, R.; De Silva, S. R.; Fred Lucena, L. M.; Meyer, E.; Metallo, S. J. Portability of a Small-Molecule Binding Site between Disordered Proteins. Biomolecules 2022, 12 (12), 1887. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_doaj_primary_oai_doaj_org_article_e7e1ef0b85354f5ea9319e9805431e82.
  3. Metallo, S. J. Intrinsically Disordered Proteins Are Potential Drug Targets. Current Opinion in Chemical Biology 2010, 14 (4), 481–488. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_2918680.

  1. Brangwynne, C. P.; Tompa, P.; Pappu, R. V. Polymer Physics of Intracellular Phase Transitions. Nature Physics 2015, 11 (11), 899–904. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_1793248190.
  2. Bujacz, A.; Bujacz, G. Crystal Structure of Bovine Serum Albumin, 2015. https://doi.org/10.2210/pdb4F5S/pdb.
  3. Bujacz, A. Structures of Bovine, Equine and Leporine Serum Albumin. Acta Crystallogr D Biol Crystallogr 2012, 68 (10), 1278–1289. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_1069205114.
  4. Davey, N. E.; Haslam, N. J.; Shields, D. C.; Edwards, R. J. SLiMSearch 2.0: Biological Context for Short Linear Motifs in Proteins. Nucleic Acids Research 2011, 39 (suppl_2), W56–W60. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3125787.
  5. Davey, N. E.; Roey, K. V.; Weatheritt, R. J.; Toedt, G.; Uyar, B.; Altenberg, B.; Budd, A.; Diella, F.; Dinkel, H.; Gibson, T. J. Attributes of Short Linear Motifs. Mol. BioSyst. 2011, 8 (1), 268–281. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_908012489.
  6. Elbaum-Garfinkle, S.; Kim, Y.; Szczepaniak, K.; Chen, C. C.-H.; Eckmann, C. R.; Myong, S.; Brangwynne, C. P. The Disordered P Granule Protein LAF-1 Drives Phase Separation into Droplets with Tunable Viscosity and Dynamics. Proceedings of the National Academy of Sciences 2015, 112 (23), 7189–7194. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4466716.
  7. Gsponer, J.; Futschik, M. E.; Teichmann, S. A.; Babu, M. M. Tight Regulation of Unstructured Proteins: From Transcript Synthesis to Protein Degradation. Science 2008, 322 (5906), 1365–1368. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_2803065.
  8. Hammoudeh, D. I.; Follis, A. V.; Prochownik, E. V.; Metallo, S. J. Multiple Independent Binding Sites for Small-Molecule Inhibitors on the Oncoprotein c-Myc. J. Am. Chem. Soc. 2009, 131 (21), 7390–7401. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_67276810.
  9. Jaiprashad, R.; De Silva, S. R.; Fred Lucena, L. M.; Meyer, E.; Metallo, S. J. Portability of a Small-Molecule Binding Site between Disordered Proteins. Biomolecules 2022, 12 (12), 1887. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_doaj_primary_oai_doaj_org_article_e7e1ef0b85354f5ea9319e9805431e82.
  10. Krystkowiak, I.; Davey, N. E. SLiMSearch: A Framework for Proteome-Wide Discovery and Annotation of Functional Modules in Intrinsically Disordered Regions. Nucleic Acids Research 2017, 45 (W1), W464–W469. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_5570202.
  11. Mittag, T.; Orlicky, S.; Choy, W.-Y.; Tang, X.; Lin, H.; Sicheri, F.; Kay, L. E.; Tyers, M.; Forman-Kay, J. D. Dynamic Equilibrium Engagement of a Polyvalent Ligand with a Single-Site Receptor. Proceedings of the National Academy of Sciences 2008, 105 (46), 17772–17777. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pnas_primary_105_46_17772.
  12. Ozenne, V.; Bauer, F.; Salmon, L.; Huang, J.; Jensen, M. R.; Segard, S.; Bernadó, P.; Charavay, C.; Blackledge, M. Flexible-Meccano: A Tool for the Generation of Explicit Ensemble Descriptions of Intrinsically Disordered Proteins and Their Associated Experimental Observables. Bioinformatics 2012, 28 (11), 1463–1470. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_1015468909.
  13. Soucek, L.; Whitfield, J.; Martins, C. P.; Finch, A. J.; Murphy, D. J.; Sodir, N. M.; Karnezis, A. N.; Swigart, L. B.; Nasi, S.; Evan, G. I. Modelling Myc Inhibition as a Cancer Therapy. Nature 2008, 455 (7213), 679–683. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4485609.
  14. Tsafou, K.; Tiwari, P. B.; Forman-Kay, J. D.; Metallo, S. J.; Toretsky, J. A. Targeting Intrinsically Disordered Transcription Factors: Changing the Paradigm. Journal of Molecular Biology 2018, 430 (16), 2321–2341. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2025806829.
  15. Uversky, V. N. Intrinsically Disordered Proteins in Overcrowded Milieu: Membrane-Less Organelles, Phase Separation, and Intrinsic Disorder. Current Opinion in Structural Biology 2017, 44, 18–30. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_1839115049.
  16. van der Lee, R.; Buljan, M.; Lang, B.; Weatheritt, R. J.; Daughdrill, G. W.; Dunker, A. K.; Fuxreiter, M.; Gough, J.; Gsponer, J.; Jones, D. T.; Kim, P. M.; Kriwacki, R. W.; Oldfield, C. J.; Pappu, R. V.; Tompa, P.; Uversky, V. N.; Wright, P. E.; Babu, M. M. Classification of Intrinsically Disordered Regions and Proteins. Chem. Rev. 2014, 114 (13), 6589–6631. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_4095912.
  17. Weissmiller, A. M.; Fesik, S. W.; Tansey, W. P. WD Repeat Domain 5 Inhibitors for Cancer Therapy: Not What You Think. Journal of Clinical Medicine 2024, 13 (1), 274. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10779565.
  18. Wells, M.; Tidow, H.; Rutherford, T. J.; Markwick, P.; Jensen, M. R.; Mylonas, E.; Svergun, D. I.; Blackledge, M.; Fersht, A. R. Structure of Tumor Suppressor P53 and Its Intrinsically Disordered N-Terminal Transactivation Domain. Proceedings of the National Academy of Sciences 2008, 105 (15), 5762–5767. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pnas_primary_105_15_5762.
  19. Wheeler, J. R.; Matheny, T.; Jain, S.; Abrisch, R.; Parker, R. Distinct Stages in Stress Granule Assembly and Disassembly. eLife 2016, 5, e18413. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_doaj_primary_oai_doaj_org_article_f21de15b53434d278f531a0c46d730c7.
  20. Wolpaw, A. J.; Bayliss, R.; Büchel, G.; Dang, C. V.; Eilers, M.; Gustafson, W. C.; Hansen, G. H.; Jura, N.; Knapp, S.; Lemmon, M. A.; Levens, D.; Maris, J. M.; Marmorstein, R.; Metallo, S. J.; Park, J. R.; Penn, L. Z.; Rape, M.; Roussel, M. F.; Shokat, K. M.; Tansey, W. P.; Verba, K. A.; Vos, S. M.; Weiss, W. A.; Wolf, E.; Mossé, Y. P. Drugging the “Undruggable” MYCN Oncogenic Transcription Factor: Overcoming Previous Obstacles to Impact Childhood Cancers. Cancer Research 2021, 81 (7), 1627–1632. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_cdl_escholarship_oai_escholarship_org_ark_13030_qt6cp3g4km.
  21. Yin, X.; Giap, C.; Lazo, J. S.; Prochownik, E. V. Low Molecular Weight Inhibitors of Myc–Max Interaction and Function. Oncogene 2003, 22 (40), 6151–6159. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_73657971.
  22. SLiMSearch | SLiMTeam. https://slim.icr.ac.uk/tools/slimsearch/input (accessed 2025-03-10).
  23. Steven Metallo. Georgetown University. https://gufaculty360.georgetown.edu/s/contact/00336000014RXoVAAW/steven-metallo (accessed 2024-12-09).

Powell Lecture:

- Professor David MacMillanMarch 21, 2025 ▼

  1. Coming Soon

  1. Coming Soon

Title to be Determined

- Aden Smigel (Student Speaker)March 28, 2025 ▼

  1. Coming Soon

  1. Coming Soon

Title to be Determined

- Parisa MershonMarch 28, 2025 ▼

  1. Coming Soon

  1. Coming Soon

Title to be Determined

- Sophie Goldberg (Student Speaker)April 4, 2025 ▼

  1. Coming Soon

  1. Coming Soon

Title to be Determined

- Marianna Vrakas (Student Speaker)April 4, 2025 ▼

  1. Coming Soon

  1. Coming Soon

Title to be Determined

- Nora Buell (Student Speaker)April 11, 2025 ▼

  1. Coming Soon

  1. Coming Soon

Title to be Determined

- Lillian Owens (Student Speaker)April 11, 2025 ▼

  1. Coming Soon

  1. Coming Soon

Synthesis of 4-isoxazolines through a one-pot heteroconjugate addition-cyclization-elimination reaction

- Mark Strigel (Student Speaker)April 11, 2025 ▼

  1. Sklar, D. E.; Helbling, A. V.; Liu, Y.; Downey, C. W. One-Pot Synthesis of 2-Methylfurans from 3-(Trimethylsilyl)Propargyl Acetates Promoted by Trimethylsilyl Trifluoromethanesulfonate. Tetrahedron Letters 2021, 87, 153424. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1016_j_tetlet_2021_153424.

  1. Coming Soon

Chemistry Seminar Presentations Archives

Over the following tabs, you will find the Chemistry Seminar listings from previous semesters. 

 Check out the Zotero Folder for Fall 2023 Chemistry Seminar Presentations. 

Sodium ion batteries rising as a key energy storage technology
- Prof. Feng Lin ▼

Characterization of Streptomyces Natural Products in New Zealand
- Pro. Jonathan Dattelbaum ▼

Non-electrophilic activators of NRF2, a transcription factor involved in the oxidative stress response
- Prof. Terry Moore ▼

Developing a Predictive Model for the Asymmetric Hydrogenation of Ketones
- Evelyn Ramirez (Student Speaker) ▼

Investigation of CO2 Reduction Mechanism with Isopropyl Amine and Other Amine Species
- Charli Chen (Student Speaker) ▼

Synthesis and Photophysics of First-Row Transition Metal Oxide Semiconductor Nanomaterials
Prof. Kathryn Knowles ▼

Organic Chemistry in Space: Formation Mechanisms and Stepwise Solvation of Astrochemical Relevant Ions in the Gas Phase
- Prof. Samy El-Shall ▼

Halogen-Bonding Capable Gold Nanoparticles — Synthesis, Modification and Application in Molecular Detection
- Karthik Lalwani (student speaker) ▼

578 Variations on the Bergman Cyclization
- Sebastian Mendoza-Gomez (student speaker) ▼

Asymmetric Synthesis of (+)-Collybolide and Reevaluation of Kappa-Opioid Receptor Agonism
- Dr. Sophie Shevick ▼

Increasing global access to the high-volume HIV drug nevirapine through process intensification
- Felix Minami (student speaker) ▼

Check out the Zotero Folder for Spring 2024 Chemistry Seminar Presentations. 

Neat, Simple, and Wrong: Just-So Stories Regarding Non-Bonded Interactions
- Dr. John Herbert ▼

Generating chiral light from molecules spanning almost the whole periodic table
- Dr. Gaël Ung ▼

  1. Adewuyi, J. A.; Schley, N. D.; Ung, G. Vanol-Supported Lanthanide Complexes for Strong Circularly Polarized Luminescence at 1550 Nm. Chemistry – A European Journal 2023, 29 (36), e202300800. https://doi.org/10.1002/chem.202300800.
  2. Arrico, L.; Di Bari, L.; Zinna, F. Quantifying the Overall Efficiency of Circularly Polarized Emitters. Chemistry – A European Journal 2021, 27 (9), 2920–2934. https://doi.org/10.1002/chem.202002791.
  3. Bailey, J.; Chrysostomou, A.; Hough, J. H.; Gledhill, T. M.; McCall, A.; Clark, S.; Ménard, F.; Tamura, M. Circular Polarization in Star- Formation Regions: Implications for Biomolecular Homochirality. Science 1998, 281 (5377), 672–674. https://doi.org/10.1126/science.281.5377.672.
  4. Chiou, T.-H.; Kleinlogel, S.; Cronin, T.; Caldwell, R.; Loeffler, B.; Siddiqi, A.; Goldizen, A.; Marshall, J. Circular Polarization Vision in a Stomatopod Crustacean. Current Biology 2008, 18 (6), 429–434. https://doi.org/10.1016/j.cub.2008.02.066.
  5. Deng, M.; Schley, N. D.; Ung, G. High Circularly Polarized Luminescence Brightness from Analogues of Shibasaki’s Lanthanide Complexes. Chem. Commun. 2020, 56 (94), 14813–14816. https://doi.org/10.1039/D0CC06568D.
  6. Gagnon, Y. L.; Templin, R. M.; How, M. J.; Marshall, N. J. Circularly Polarized Light as a Communication Signal in Mantis Shrimps. Current Biology 2015, 25 (23), 3074–3078. https://doi.org/10.1016/j.cub.2015.10.047.
  7. Near-Infrared (NIR) Luminescence from Lanthanide(III) Complexes. In Rare earth coordination chemistry: fundamentals and applications; Huang, C.-H., Ed.; John Wiley& Sons: Singapore ; Hoboken, NJ, 2010.
  8. Kleinlogel, S.; White, A. G. The Secret World of Shrimps: Polarisation Vision at Its Best. PLoS One 2008, 3 (5), e2190. https://doi.org/10.1371/journal.pone.0002190.
  9. Kwon, J.; Nakagawa, T.; Tamura, M.; Hough, J. H.; Kandori, R.; Choi, M.; Kang, M.; Cho, J.; Nakajima, Y.; Nagata, T. Near-Infrared Polarimetry of the Outflow Source AFGL 6366S: Detection of Circular Polarization. AJ 2018, 156 (1), 1. https://doi.org/10.3847/1538-3881/aac389.
  10. Mukthar, N. F. M.; Schley, N. D.; Ung, G. Strong Circularly Polarized Luminescence at 1550 Nm from Enantiopure Molecular Erbium Complexes. J. Am. Chem. Soc. 2022, 144 (14), 6148–6153. https://doi.org/10.1021/jacs.2c01134.
  11. Schnable, D.; Ung, G. Augmentation of NIR Circularly Polarized Luminescence Activity in Shibasaki-Type Lanthanide Complexes Supported by the Spirane Sphenol, 2024. https://ung.chem.uconn.edu/pubs/.
  12. Sharma, V.; Crne, M.; Park, J. O.; Srinivasarao, M. Structural Origin of Circularly Polarized Iridescence in Jeweled Beetles. Science 2009, 325 (5939), 449–451. https://doi.org/10.1126/science.1172051.
  13. Willis, B.-A. N.; Schnable, D.; Schley, N. D.; Ung, G. Spinolate Lanthanide Complexes for High Circularly Polarized Luminescence Metrics in the Visible and Near-Infrared. J. Am. Chem. Soc. 2022, 144 (49), 22421–22425. https://doi.org/10.1021/jacs.2c10364.
  14. Wynberg, H.; Meijer, E. W.; Hummelen, J. C.; Dekkers, H. P. J. M.; Schippers, P. H.; Carlson, A. D. Circular Polarization Observed in Bioluminescence. Nature 1980, 286 (5773), 641–642. https://doi.org/10.1038/286641a0.
  15. Ung Research Group. University of Connecticut. https://ung.chem.uconn.edu/.

Rhodium-Catalyzed C–H Activation for the Synthesis, Elaboration, and Application of N-Heterocyclic Compounds
- Dr. Danielle Confair ▼

  1. Colby, D. A.; Bergman, R. G.; Ellman, J. A. Synthesis of Dihydropyridines and Pyridines from Imines and Alkynes via C−H Activation. J. Am. Chem. Soc. 2008, 130 (11), 3645–3651. https://doi.org/10.1021/ja7104784.
  2. Colby, D. A.; Bergman, R. G.; Ellman, J. A. Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation. Chem. Rev. 2010, 110 (2), 624–655. https://doi.org/10.1021/cr900005n.
  3. Confair, D. N.; Greenwood, N. S.; Mercado, B. Q.; Ellman, J. A. Rh(III)-Catalyzed Imidoyl C–H Carbamylation and Cyclization to Bicyclic [1,3,5]Triazinones. Org. Lett. 2020, 22 (22), 8993–8997. https://doi.org/10.1021/acs.orglett.0c03393.
  4. Das, S.; Addis, D.; Zhou, S.; Junge, K.; Beller, M. Zinc-Catalyzed Reduction of Amides: Unprecedented Selectivity and Functional Group Tolerance. J. Am. Chem. Soc. 2010, 132 (13), 4971–4971. https://doi.org/10.1021/ja101189c.
  5. Downey, C. W.; Confair, D. N.; Liu, Y.; Heafner, E. D. One-Pot Enol Silane Formation–Alkylation of Ketones with Propargyl Carboxylates Promoted by Trimethylsilyl Trifluoromethanesulfonate. J. Org. Chem. 2018, 83 (20), 12931–12938. https://doi.org/10.1021/acs.joc.8b01997.
  6. Downey, C. W.; Maxwell, E. N.; Confair, D. N. Silyl Triflate-Accelerated Additions of Catalytically Generated Zinc Acetylides to N-Phenyl Nitrones. Tetrahedron Letters 2014, 55 (35), 4959–4961. https://doi.org/10.1016/j.tetlet.2014.07.015.
  7. Duttwyler, S.; Chen, S.; Takase, M. K.; Wiberg, K. B.; Bergman, R. G.; Ellman, J. A. Proton Donor Acidity Controls Selectivity in Nonaromatic Nitrogen Heterocycle Synthesis. Science 2013, 339 (6120), 678–682.
  8. Duttwyler, S.; Lu, C.; Rheingold, A. L.; Bergman, R. G.; Ellman, J. A. Highly Diastereoselective Synthesis of Tetrahydropyridines by a C–H Activation–Cyclization–Reduction Cascade. J. Am. Chem. Soc. 2012, 134 (9), 4064–4067. https://doi.org/10.1021/ja2119833.
  9. Fukui, M.; Rodriguiz, R. M.; Zhou, J.; Jiang, S. X.; Phillips, L. E.; Caron, M. G.; Wetsel, W. C. Vmat2 Heterozygous Mutant Mice Display a Depressive-Like Phenotype. J. Neurosci. 2007, 27 (39), 10520–10529. https://doi.org/10.1523/JNEUROSCI.4388-06.2007.
  10. Ghosh, E.; Kumari, P.; Jaiman, D.; Shukla, A. K. Methodological Advances: The Unsung Heroes of the GPCR Structural Revolution. Nat Rev Mol Cell Biol 2015, 16 (2), 69–81. https://doi.org/10.1038/nrm3933.
  11. Hauser, A. S.; Attwood, M. M.; Rask-Andersen, M.; Schiöth, H. B.; Gloriam, D. E. Trends in GPCR Drug Discovery: New Agents, Targets and Indications. Nat Rev Drug Discov 2017, 16 (12), 829–842. https://doi.org/10.1038/nrd.2017.178.
  12. Kaplan, A. L.; Confair, D. N.; Kim, K.; Barros-álvarez, X.; Rodriguiz, R. M.; Yang, Y.; Kweon, O. S.; Che, T.; McCorvy, J. D.; Kamber, D. N.; Phelan, J. P.; Martins, L. C.; Pogorelov, V. M.; Diberto, J. F.; Slocum, S. T.; Huang, X.-P.; Kumar, J. M.; Robertson, M. J.; Panova, O.; Seven, A. B.; Wetsel, A. Q.; Wetsel, W. C.; Irwin, J. J.; Skiniotis, G.; Shoichet, B. K.; Roth, B. L.; Ellman, J. A. Bespoke Library Docking for 5-HT2A Receptor Agonists with Antidepressant Activity. Nature 2022, 610 (7932), 582-3,591A-591W. https://doi.org/10.1038/s41586-022-05258-z.
  13. Kooistra, A. J.; Mordalski, S.; Pándy-Szekeres, G.; Esguerra, M.; Mamyrbekov, A.; Munk, C.; Keserű, G. M.; Gloriam, D. E. GPCRdb in 2021: Integrating GPCR Sequence, Structure and Function. Nucleic Acids Research 2021, 49 (D1), D335–D343. https://doi.org/10.1093/nar/gkaa1080.
  14. Nutt, D.; Erritzoe, D.; Carhart-Harris, R. Psychedelic Psychiatry’s Brave New World. Cell 2020, 181 (1), 24–28. https://doi.org/10.1016/j.cell.2020.03.020.
  15. Rodriguiz, R. M.; Nadkarni, V.; Means, C. R.; Pogorelov, V. M.; Chiu, Y.-T.; Roth, B. L.; Wetsel, W. C. LSD-Stimulated Behaviors in Mice Require β-Arrestin 2 but Not β-Arrestin 1. Sci Rep 2021, 11 (1), 17690. https://doi.org/10.1038/s41598-021-96736-3.
  16. Rogge, T.; Kaplaneris, N.; Chatani, N.; Kim, J.; Chang, S.; Punji, B.; Schafer, L. L.; Musaev, D. G.; Wencel-Delord, J.; Roberts, C. A.; Sarpong, R.; Wilson, Z. E.; Brimble, M. A.; Johansson, M. J.; Ackermann, L. C–H Activation. Nat Rev Methods Primers 2021, 1 (1), 1–31. https://doi.org/10.1038/s43586-021-00041-2.
  17. Roth, B. L. Irving Page Lecture: 5-HT2A Serotonin Receptor Biology: Interacting Proteins, Kinases and Paradoxical Regulation. Neuropharmacology 2011, 61 (3), 348–354. https://doi.org/10.1016/j.neuropharm.2011.01.012.
  18. Sambiagio, C.; Schönbauer, D.; Blieck, R.; Dao-Huy, T.; Pototschnig, G.; Schaaf, P.; Wiesinger, T.; Zia, M. F.; Wencel-Delord, J.; Besset, T.; Maes, B. U. W.; Schnürch, M. A Comprehensive Overview of Directing Groups Applied in Metal-Catalysed C–H Functionalisation Chemistry. Chem. Soc. Rev. 2018, 47 (17), 6603–6743. https://doi.org/10.1039/C8CS00201K.
  19. Tran, G.; Confair, D.; Hesp, K. D.; Mascitti, V.; Ellman, J. A. C2-Selective Branched Alkylation of Benzimidazoles by Rhodium(I)-Catalyzed C–H Activation. J. Org. Chem. 2017, 82 (17), 9243–9252. https://doi.org/10.1021/acs.joc.7b01723.
  20. Vitaku, E.; Smith, D. T.; Njardarson, J. T. Analysis of the Structural Diversity, Substitution Patterns, and Frequency of Nitrogen Heterocycles among U.S. FDA Approved Pharmaceuticals. J. Med. Chem. 2014, 57 (24), 10257–10274. https://doi.org/10.1021/jm501100b.
  21. Yang, B. V.; O’Rourke, D.; Li, J. Mild and Selective Debenzylation of Tertiary Amines Using α-Chloroethyl Chloroformate. Synlett 1993, 1993 (3), 195–196. https://doi.org/10.1055/s-1993-22398.
  22. Ellman Laboratory. Yale University. https://ellman.chem.yale.edu/.
  23. Downey Group. University of Richmond. https://blog.richmond.edu/downey/.

The Global Energy Challenge: Food and Fuel from Air, Water and Sunlight
- Dr. Daniel Nocera ▼

  1. Alfaraidi, A. M.; Kudisch, B.; Ni, N.; Thomas, J.; George, T. Y.; Rajabimoghadam, K.; Jiang, H. J.; Nocera, D. G.; Aziz, M. J.; Liu, R. Y. Reversible CO2 Capture and On-Demand Release by an Acidity-Matched Organic Photoswitch. J. Am. Chem. Soc. 2023, 145 (49), 26720–26727. https://doi.org/10.1021/jacs.3c08471.
  2. Campbell, B. M.; Gordon, J. B.; Raguram, E. R.; Gonzalez, M. I.; Reynolds, K. G.; Nava, M.; Nocera, D. G. Electrophotocatalytic Perfluoroalkylation by LMCT Excitation of Ag(II) Perfluoroalkyl Carboxylates. Science 2024, 383 (6680), 279–284. https://doi.org/10.1126/science.adk4919.
  3. Johnston, B.; Loh, D. M.; Nocera, D. G. Substrate-Mediator Duality of 1,4-Dicyanobenzene in Electrochemical C(Sp2)−C(Sp3) Bond Formation with Alkyl Bromides. Angewandte Chemie International Edition 2023, 62 (49), e202312128. https://doi.org/10.1002/anie.202312128.
  4. Keane, T. P.; Veroneau, S. S.; Hartnett, A. C.; Nocera, D. G. Generation of Pure Oxygen from Briny Water by Binary Catalysis. J. Am. Chem. Soc. 2023, 145 (9), 4989–4993. https://doi.org/10.1021/jacs.3c00176.
  5. Lemon, C. M.; Powers, D. C.; Huynh, M.; Maher, A. G.; Phillips, A. A.; Tripet, B. P.; Nocera, D. G. Ag(III)···Ag(III) Argentophilic Interaction in a Cofacial Corrole Dyad. Inorg. Chem. 2023, 62 (1), 3–17. https://doi.org/10.1021/acs.inorgchem.2c02285.
  6. Sun, R.; Ruccolo, S.; Nascimento, D. L.; Qin, Y.; Hibbert, N.; Nocera, D. G. Chemoselective Bond Activation by Unidirectional and Asynchronous PCET Using Ketone Photoredox Catalysts. Chem. Sci. 2023, 14 (47), 13776–13782. https://doi.org/10.1039/D3SC04362B.
  7. Veroneau, S. S.; Thorarinsdottir, A. E.; Loh, D. M.; Hartnett, A. C.; Keane, T. P.; Nocera, D. G. Electrolyte-Induced Restructuring of Acid-Stable Oxygen Evolution Catalysts. Chem. Mater. 2023, 35 (8), 3218–3225. https://doi.org/10.1021/acs.chemmater.3c00032.
  8. Yan, Z.; Reynolds, K. G.; Sun, R.; Shin, Y.; Thorarinsdottir, A. E.; Gonzalez, M. I.; Kudisch, B.; Galli, G.; Nocera, D. G. Oxidation Chemistry of Bicarbonate and Peroxybicarbonate: Implications for Carbonate Management in Energy Storage. J. Am. Chem. Soc. 2023, 145 (40), 22213–22221. https://doi.org/10.1021/jacs.3c08144.
  9. Zhu, Q.; Costentin, C.; Stubbe, J.; Nocera, D. G. Disulfide Radical Anion as a Super-Reductant in Biology and Photoredox Chemistry. Chem. Sci. 2023, 14 (25), 6876–6881. https://doi.org/10.1039/D3SC01867A.

Quantifying and Partitioning Substituent Effects using Sigma Hole Potentials
- Nam Pham (student speaker) ▼

Effects of polymer solution entanglement on the mechanics of electrospun polycaprolactone fibers
- Manasa Rajeev (student speaker) ▼

New Synthetic Methods for Deoxygenative Diversification for Carboxylic Acids
- Byoungmoo Kim ▼

  1. Bower, S.; Kreutzer, K. A.; Buchwald, S. L. A Mild General Procedure for the One-Pot Conversion of Amides to Aldehydes. Angewandte Chemie International Edition in English 1996, 35 (13–14), 1515–1516. https://doi.org/10.1002/anie.199615151.
  2. Chandrika, N. T.; Garneau-Tsodikova, S. Comprehensive Review of Chemical Strategies for the Preparation of New Aminoglycosides and Their Biological Activities. Chem. Soc. Rev. 2018, 47 (4), 1189–1249. https://doi.org/10.1039/C7CS00407A.
  3. Feng, M.; Zhang, H.; Maulide, N. Challenges and Breakthroughs in Selective Amide Activation. Angewandte Chemie International Edition 2022, 61 (49), e202212213. https://doi.org/10.1002/anie.202212213.
  4. Hartwig, J. F. Catalyst-Controlled Site-Selective Bond Activation. Acc. Chem. Res. 2017, 50 (3), 549–555. https://doi.org/10.1021/acs.accounts.6b00546.
  5. Huang, Z.; Dong, G. Site-Selectivity Control in Organic Reactions: A Quest To Differentiate Reactivity among the Same Kind of Functional Groups. Acc. Chem. Res. 2017, 50 (3), 465–471. https://doi.org/10.1021/acs.accounts.6b00476.
  6. Katsuki, T.; Sharpless, K. B. The First Practical Method for Asymmetric Epoxidation. J. Am. Chem. Soc. 1980, 102 (18), 5974–5976. https://doi.org/10.1021/ja00538a077.
  7. Krueger, C. A.; Kuntz, K. W.; Dzierba, C. D.; Wirschun, W. G.; Gleason, J. D.; Snapper, M. L.; Hoveyda, A. H. Ti-Catalyzed Enantioselective Addition of Cyanide to Imines. A Practical Synthesis of Optically Pure α-Amino Acids. J. Am. Chem. Soc. 1999, 121 (17), 4284–4285. https://doi.org/10.1021/ja9840605.
  8. Kumari, S.; Carmona, A. V.; Tiwari, A. K.; Trippier, P. C. Amide Bond Bioisosteres: Strategies, Synthesis, and Successes. J. Med. Chem. 2020, 63 (21), 12290–12358. https://doi.org/10.1021/acs.jmedchem.0c00530.
  9. Le, D. N.; Hansen, E.; Khan, H. A.; Kim, B.; Wiest, O.; Dong, V. M. Hydrogenation Catalyst Generates Cyclic Peptide Stereocentres in Sequence. Nature Chem 2018, 10 (9), 968–973. https://doi.org/10.1038/s41557-018-0089-5.
  10. Liu, Y.; Kim, B.; Taylor, S. D. Synthesis of 4-Formyl Estrone Using a Positional Protecting Group and Its Conversion to Other C-4-Substituted Estrogens. J. Org. Chem. 2007, 72 (23), 8824–8830. https://doi.org/10.1021/jo7017075.
  11. Matheau-Raven, D.; Gabriel, P.; Leitch, J. A.; Almehmadi, Y. A.; Yamazaki, K.; Dixon, D. J. Catalytic Reductive Functionalization of Tertiary Amides Using Vaska’s Complex: Synthesis of Complex Tertiary Amine Building Blocks and Natural Products. ACS Catal. 2020, 10 (15), 8880–8897. https://doi.org/10.1021/acscatal.0c02377.
  12. Newman, D. J.; Cragg, G. M. Natural Products as Sources of New Drugs over the Nearly Four Decades from 01/1981 to 09/2019. J. Nat. Prod. 2020, 83 (3), 770–803. https://doi.org/10.1021/acs.jnatprod.9b01285.
  13. Phan, D. H. T.; Kim, B.; Dong, V. M. Phthalides by Rhodium-Catalyzed Ketone Hydroacylation. J. Am. Chem. Soc. 2009, 131 (43), 15608–15609. https://doi.org/10.1021/ja907711a.
  14. Shugrue, C. R.; Miller, S. J. Applications of Nonenzymatic Catalysts to the Alteration of Natural Products. Chem. Rev. 2017, 117 (18), 11894–11951. https://doi.org/10.1021/acs.chemrev.7b00022.
  15. Toste, F. D.; Sigman, M. S.; Miller, S. J. Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis. Acc. Chem. Res. 2017, 50 (3), 609–615. https://doi.org/10.1021/acs.accounts.6b00613.
  16. Trillo, P.; Adolfsson, H. Direct Catalytic Reductive N-Alkylation of Amines with Carboxylic Acids: Chemoselective Enamine Formation and Further Functionalizations. ACS Catal. 2019, 9 (8), 7588–7595. https://doi.org/10.1021/acscatal.9b01974.
  17. The Kim Group | Synthetic Organic Chemistry and Catalysis. Clemson University. https://scienceweb.clemson.edu/kimgroup/.

One-pot enol silane formation — allylation of ketones promoted by trimethylsilyl trifluoromethanesulfonate
- Alexa Connors (student speaker) ▼

The Effect of Solvent Identity and Hydride-Donor on the Reduction of CO2 into Useful Fuels
- Abigail McEntire (student speaker) ▼

  1. Feaster, J. T.; Shi, C.; Cave, E. R.; Hatsukade, T.; Abram, D. N.; Kuhl, K. P.; Hahn, C.; Nørskov, J. K.; Jaramillo, T. F. Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes. ACS Catal. 2017, 7 (7), 4822–4827. https://doi.org/10.1021/acscatal.7b00687.
  2. Gao, F.-Y.; Bao, R.-C.; Gao, M.-R.; Yu, S.-H. Electrochemical CO2-to-CO Conversion: Electrocatalysts, Electrolytes, and Electrolyzers. J. Mater. Chem. A 2020, 8 (31), 15458–15478. https://doi.org/10.1039/D0TA03525D.
  3. Graham, D. SOP4CV - Standard Operating Procedures for Cyclic Voltammetry; 2017. https://sop4cv.com/. 
  4. Karak, P.; Mandal, S. K.; Choudhury, J. Bis-Imidazolium-Embedded Heterohelicene: A Regenerable NADP+ Cofactor Analogue for Electrocatalytic CO2 Reduction. J. Am. Chem. Soc. 2023, 145 (13), 7230–7241. https://doi.org/10.1021/jacs.2c12883.
  5. Min, X.; Kanan, M. W. Pd-Catalyzed Electrohydrogenation of Carbon Dioxide to Formate: High Mass Activity at Low Overpotential and Identification of the Deactivation Pathway. J. Am. Chem. Soc. 2015, 137 (14), 4701–4708. https://doi.org/10.1021/ja511890h.
  6. Rosen, J.; Hutchings, G. S.; Lu, Q.; Forest, R. V.; Moore, A.; Jiao, F. Electrodeposited Zn Dendrites with Enhanced CO Selectivity for Electrocatalytic CO2 Reduction. ACS Catal. 2015, 5 (8), 4586–4591. https://doi.org/10.1021/acscatal.5b00922.
  7. Torbensen, K.; Joulié, D.; Ren, S.; Wang, M.; Salvatore, D.; Berlinguette, C. P.; Robert, M. Molecular Catalysts Boost the Rate of Electrolytic CO2 Reduction. ACS Energy Lett. 2020, 5 (5), 1512–1518. https://doi.org/10.1021/acsenergylett.0c00536.

Identification of Xanthones as Selective Killers of CancerCells Overexpressing the ABC Transporter MRP1
- Kathy Colin (student speaker) ▼

  1. CAS, a division of the American Chemical Society. Glutathione. CAS Common Chemistry. https://commonchemistry.cas.org/detail?cas_rn=70-18-8&search=glutathione.
  2. CAS, a division of the American Chemical Society. Verapamil. CAS Common Chemistry. https://commonchemistry.cas.org/detail?cas_rn=52-53-9&search=verapamil.
  3. CAS, a division of the American Chemical Society. Xanthone. CAS Common Chemistry. https://commonchemistry.cas.org/detail?cas_rn=90-47-1&search=xanthone.
  4. EUPATI. Pharmacokinetics; n.d. https://toolbox.eupati.eu/glossary/pharmacokinetics/.
  5. Thurm, C.; Schraven, B.; Kahlfuss, S. ABC Transporters in T Cell-Mediated Physiological and Pathological Immune Responses. IJMS 2021, 22 (17), 9186. https://doi.org/10.3390/ijms22179186.
  6. World Health Organization. Global Tuberculosis Report 2014; World Health Organization: Geneva, 2014. https://iris.who.int/handle/10665/137094.
  7. Zhou, S. F. Role of Multidrug Resistance Associated Proteins in Drug Development. Drug Discov Ther 2008, 2 (6), 305–332.
  8. Pollock Research Lab. University of Richmond. https://blog.richmond.edu/pollocklab/.
  9. Student Programs. AbbVie. https://www.abbvie.com/join-us/opportunities/student-programs.html.
  10. Undergraduate Research in Chemical Biology. Vanderbilt College of Arts and Science. https://www.vanderbilt.edu/reu/index.php.

Exploration of Pynaphthyridine and Binaphthyridine Manganese(I) Tricarbonyl Complexes: Influence on Carbon Dioxide Reduction Electrocatalysis
- Luke Simkins (student speaker) ▼

  1. Cohen, K.; Simonyan, H.; Ortiz, M.; Solomon, B.; Simkins, L.; Dominey, R.; Goldman, E.; Bocarsly, A. Exploration of Pynaphthyridine and Binaphthyridine Manganese(I) Tricarbonyl Complexes: Influence on Carbon Dioxide Reduction Electrocatalysis. 
    • submitted to Organometallics

  1. Lüthi, D.; Le Floch, M.; Bereiter, B.; Blunier, T.; Barnola, J.-M.; Siegenthaler, U.; Raynaud, D.; Jouzel, J.; Fischer, H.; Kawamura, K.; Stocker, T. F. High-Resolution Carbon Dioxide Concentration Record 650,000–800,000 Years before Present. Nature 2008, 453 (7193), 379–382. https://doi.org/10.1038/nature06949.
  2. MacFarling Meure, C.; Etheridge, D.; Trudinger, C.; Steele, P.; Langenfelds, R.; van Ommen, T.; Smith, A.; Elkins, J. Law Dome CO2, CH4 and N2O Ice Core Records Extended to 2000 Years BP. Geophysical Research Letters 2006, 33 (14). https://doi.org/10.1029/2006GL026152.
  3. Neftel, A.; Moor, E.; Oeschger, H.; Stauffer, B. Evidence from Polar Ice Cores for the Increase in Atmospheric CO2 in the Past Two Centuries. Nature 1985, 315 (6014), 45–47. https://doi.org/10.1038/315045a0.
  4. Petit, J. R.; Jouzel, J.; Raynaud, D.; Barkov, N. I.; Barnola, J.-M.; Basile, I.; Bender, M.; Chappellaz, J.; Davis, M.; Delaygue, G.; Delmotte, M.; Kotlyakov, V. M.; Legrand, M.; Lipenkov, V. Y.; Lorius, C.; PÉpin, L.; Ritz, C.; Saltzman, E.; Stievenard, M. Climate and Atmospheric History of the Past 420,000 Years from the Vostok Ice Core, Antarctica. Nature 1999, 399 (6735), 429–436. https://doi.org/10.1038/20859.
  5. Rubino, M.; Etheridge, D. M.; Trudinger, C. M.; Allison, C. E.; Battle, M. O.; Langenfelds, R. L.; Steele, L. P.; Curran, M.; Bender, M.; White, J. W. C.; Jenk, T. M.; Blunier, T.; Francey, R. J. A Revised 1000 Year Atmospheric δ13C-CO2 Record from Law Dome and South Pole, Antarctica. Journal of Geophysical Research: Atmospheres 2013, 118 (15), 8482–8499. https://doi.org/10.1002/jgrd.50668.
  6. Siegenthaler, U.; Stocker, T. F.; Monnin, E.; Lüthi, D.; Schwander, J.; Stauffer, B.; Raynaud, D.; Barnola, J.-M.; Fischer, H.; Masson-Delmotte, V.; Jouzel, J. Stable Carbon Cycle-Climate Relationship During the Late Pleistocene. Science 2005, 310 (5752), 1313–1317. https://doi.org/10.1126/science.1120130.
  7. Home | Scripps CO2 Program. https://scrippsco2.ucsd.edu/.

The Continuous Flow Synthesis of Polyfunctionalized Pyrroles
- Kingsley Dwomoh (student speaker) ▼

  1. CAS, a division of the American Chemical Society. (Chloromethylene)dimethylammonium chloride. CAS Common Chemistry. https://commonchemistry.cas.org/detail?cas_rn=3724-43-4.
  2. Giles, P. R.; Marson, C. M. Dimethylchloromethyleneammonium Chloride. In Encyclopedia of Reagents for Organic Synthesis; John Wiley & Sons, Ltd, 2001. https://doi.org/10.1002/047084289X.rd319m.

Comparison of properties of isomeric pyrrolyl phosphine ligands
- Vicky Osenga (student speaker) ▼

Altering Product Selectivity for Ru-based CO2 Reduction Catalysts
- Ben Dwyer (student speaker) ▼

One-pot synthesis of 4-isoxazolines from chalcones promoted by trimethylsilyl trifluoromethanesulfonate
- Greg Hughes (student speaker) ▼

Substitution of sulfur-containing compounds
- Abigail Dalton (student speaker) ▼

Acrylic Copolymer Structures from Photoredox-Mediated RAFT Polymerizations
- Professor Adrian FiggSeptember 6, 2024 ▼

  1. Baker, J. G.; Zhang, R.; Figg, C. A. Installing a Single Monomer within Acrylic Polymers Using Photoredox Catalysis. J. Am. Chem. Soc. 2024, 146 (1), 106–111. https://doi.org/10.1021/jacs.3c12221. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2905524757.

  1. Elling, B. R.; Su, J. K.; Feist, J. D.; Xia, Y. Precise Placement of Single Monomer Units in Living Ring-Opening Metathesis Polymerization. Chem 2019, 5 (10), 2691–2701. https://doi.org/10.1016/j.chempr.2019.07.017.
  2. Flory, P. J. Principles of Polymer Chemistry.; The George Fisher Baker non-resident lectureship in chemistry at Cornell University; Cornell University Press: Ithaca, 1953.
  3. Foster, J. C.; Damron, J. T.; Zhang, H. Simple Monomers for Precise Polymer Functionalization During Ring-Opening Metathesis Polymerization. Macromolecules 2023, 56 (19), 7931–7938. https://doi.org/10.1021/acs.macromol.3c01068.
  4. Gruendling, T.; Kaupp, M.; Blinco, J. P.; Barner-Kowollik, C. Photoinduced Conjugation of Dithioester- and Trithiocarbonate-Functional RAFT Polymers with Alkenes. Macromolecules 2011, 44 (1), 166–174. https://doi.org/10.1021/ma101893u.
  5. Huang, Z.; Noble, B. B.; Corrigan, N.; Chu, Y.; Satoh, K.; Thomas, D. S.; Hawker, C. J.; Moad, G.; Kamigaito, M.; Coote, M. L.; Boyer, C.; Xu, J. Discrete and Stereospecific Oligomers Prepared by Sequential and Alternating Single Unit Monomer Insertion. J. Am. Chem. Soc. 2018, 140 (41), 13392–13406. https://doi.org/10.1021/jacs.8b08386.
  6. Kaminsky, W. Olefin Polymerization Catalyzed by Metallocenes1. In Advances in Catalysis; Academic Press, 2001; Vol. 46, pp 89–159. https://doi.org/10.1016/S0360-0564(02)46022-1.
  7. Moriceau, G.; Gody, G.; Hartlieb, M.; Winn, J.; Kim, H.; Mastrangelo, A.; Smith, T.; Perrier, S. Functional Multisite Copolymer by One-Pot Sequential RAFT Copolymerization of Styrene and Maleic Anhydride. Polym. Chem. 2017, 8 (28), 4152–4161. https://doi.org/10.1039/C7PY00787F.
  8. Shanmugam, S.; Xu, J.; Boyer, C. Light-Regulated Polymerization under Near-Infrared/Far-Red Irradiation Catalyzed by Bacteriochlorophyll a. Angewandte Chemie International Edition 2016, 55 (3), 1036–1040. https://doi.org/10.1002/anie.201510037.
  9. Silva, T. B.; Spulber, M.; Kocik, M. K.; Seidi, F.; Charan, H.; Rother, M.; Sigg, S. J.; Renggli, K.; Kali, G.; Bruns, N. Hemoglobin and Red Blood Cells Catalyze Atom Transfer Radical Polymerization. Biomacromolecules 2013, 14 (8), 2703–2712. https://doi.org/10.1021/bm400556x.
  10. Simakova, A.; Mackenzie, M.; Averick, S. E.; Park, S.; Matyjaszewski, K. Bioinspired Iron-Based Catalyst for Atom Transfer Radical Polymerization. Angewandte Chemie International Edition 2013, 52 (46), 12148–12151. https://doi.org/10.1002/anie.201306337.
  11. Vandenbergh, J.; Reekmans, G.; Adriaensens, P.; Junkers, T. Synthesis of Sequence Controlled Acrylate Oligomers via Consecutive RAFT Monomer Additions. Chem. Commun. 2013, 49 (88), 10358–10360. https://doi.org/10.1039/C3CC45994B.
  12. Zamfir, M.; Lutz, J.-F. Ultra-Precise Insertion of Functional Monomers in Chain-Growth Polymerizations. Nat Commun 2012, 3 (1), 1138. https://doi.org/10.1038/ncomms2151.
  13. Zhou, F.; Li, R.; Wang, X.; Du, S.; An, Z. Non-Natural Photoenzymatic Controlled Radical Polymerization Inspired by DNA Photolyase. Angewandte Chemie International Edition 2019, 58 (28), 9479–9484. https://doi.org/10.1002/anie.201904413.
  14. Figg Research Group. Virginia Tech. https://figglab.com (accessed 2024-09-10).
  15. Adrian Figg. Virginia Tech. https://chem.vt.edu/content/chem_vt_edu/en/people/faculty/teaching-and-research/afigg.html (accessed 2024-09-10).

Exploring Next-Generation Quantum Chemistry Calculations: Leveraging a Toolbox with Grassmannians, Fragmentation, and Machine Learning
- Professor Ka Un LauSeptember 13, 2024 ▼

  1. Piela, L. Ideas of Quantum Chemistry, Third edition.; Elsevier: Amsterdam, Netherlands ; Cambridge, MA, United States, 2020.
  2. Al-Hamdani, Y. S.; Nagy, P. R.; Zen, A.; Barton, D.; Kállay, M.; Brandenburg, J. G.; Tkatchenko, A. Interactions between Large Molecules Pose a Puzzle for Reference Quantum Mechanical Methods. Nat Commun 2021, 12 (1), 3927. https://doi.org/10.1038/s41467-021-24119-3.
  3. Ballesteros, F.; Lao, K. U. Accelerating the Convergence of Self-Consistent Field Calculations Using the Many-Body Expansion. J. Chem. Theory Comput. 2022, 18 (1), 179–191. https://doi.org/10.1021/acs.jctc.1c00765.
  4. Chen, J.; Ahasan, M. R.; Oh, J.-S.; Tan, J. A.; Hennessey, S.; Kaid, M. M.; El-Kaderi, H. M.; Zhou, L.; Lao, K. U.; Wang, R.; Wang, W.-N. Highly Efficient CO 2 Electrochemical Reduction on Dual Metal (Co–Ni)–Nitrogen Sites. J. Mater. Chem. A 2024, 12 (8), 4601–4609. https://doi.org/10.1039/D3TA05654F.
  5. Clark, T. M.; Anderson, E.; Dickson-Karn, N. M.; Soltanirad, C.; Tafini, N. Comparing the Performance of College Chemistry Students with ChatGPT for Calculations Involving Acids and Bases. J. Chem. Educ. 2023, 100 (10), 3934–3944. https://doi.org/10.1021/acs.jchemed.3c00500.
  6. Folmsbee, D.; Hutchison, G. Assessing Conformer Energies Using Electronic Structure and Machine Learning Methods. Int J of Quantum Chemistry 2021, 121 (1), e26381. https://doi.org/10.1002/qua.26381.
  7. Fu, X.; Wu, Z.; Wang, W.; Xie, T.; Keten, S.; Gomez-Bombarelli, R.; Jaakkola, T. S. Forces Are Not Enough: Benchmark and Critical Evaluation for Machine Learning Force Fields with Molecular Simulations. Transactions on Machine Learning Research 2023.
  8. Graves, L. S.; Sarkar, R.; Baker, J.; Lao, K. U.; Arachchige, I. U. Structure- and Morphology-Controlled Synthesis of Hexagonal Ni 2– x Zn x P Nanocrystals and Their Composition-Dependent Electrocatalytic Activity for Hydrogen Evolution Reaction. ACS Appl. Energy Mater. 2024, 7 (14), 5679–5690. https://doi.org/10.1021/acsaem.4c00539.
  9. Graves, L. S.; Sarkar, R.; Lao, K. U.; Arachchige, I. U. Composition-Dependent Electrocatalytic Activity of Zn-Doped Ni 5 P 4 Nanocrystals for the Hydrogen Evolution Reaction. Chem. Mater. 2023, 35 (17), 6966–6978. https://doi.org/10.1021/acs.chemmater.3c01229.
  10. Le Breton, G.; Bonhomme, O.; Benichou, E.; Loison, C. FROG: Exploiting All-Atom Molecular Dynamics Trajectories to Calculate Linear and Non-Linear Optical Responses of Molecular Liquids within Dalton’s QM/MM Polarizable Embedding Scheme. The Journal of Chemical Physics 2024, 160 (19), 194103. https://doi.org/10.1063/5.0203424.
  11. Li, W.; Wang, D.; Lao, K. U.; Wang, X. Buffer Concentration Dramatically Affects the Stability of S-Nitrosothiols in Aqueous Solutions. Nitric Oxide 2022, 118, 59–65. https://doi.org/10.1016/j.niox.2021.11.002.
  12. Li, W.; Wang, D.; Lao, K. U.; Wang, X. Inclusion Complexation of S -Nitrosoglutathione for Sustained Nitric Oxide Release from Catheter Surfaces: A Strategy to Prevent and Treat Device-Associated Infections. ACS Biomater. Sci. Eng. 2023, 9 (3), 1694–1705. https://doi.org/10.1021/acsbiomaterials.2c01284.
  13. López Peña, H. A.; Shusterman, J. M.; Ampadu Boateng, D.; Lao, K. U.; Tibbetts, K. M. Coherent Control of Molecular Dissociation by Selective Excitation of Nuclear Wave Packets. Front. Chem. 2022, 10, 859095. https://doi.org/10.3389/fchem.2022.859095.
  14. López Peña, H. A.; Shusterman, J. M.; Dalkiewicz, C.; McPherson, S. L.; Dunstan, C.; Sangroula, K.; Lao, K. U.; Tibbetts, K. M. Photodissociation Dynamics of the Highly Stable Ortho -Nitroaniline Cation. J. Phys. Chem. A 2024, 128 (9), 1634–1645. https://doi.org/10.1021/acs.jpca.3c08364.
  15. Mason, K. A.; Pearcy, A. C.; Lao, K. U.; Christensen, Z. A.; El-Shall, M. S. Non-Covalent Interactions of Hydrogen Cyanide and Acetonitrile with the Quinoline Radical Cation via Ionic Hydrogen Bonding. Chemical Physics Letters 2020, 754, 137744. https://doi.org/10.1016/j.cplett.2020.137744.
  16. Ng, K. C.; Adel, T.; Lao, K. U.; Varmecky, M. G.; Liu, Z.; Arrad, M.; Allen, H. C. Iron(III) Chloro Complexation at the Air–Aqueous FeCl 3 Interface via Second Harmonic Generation Spectroscopy. J. Phys. Chem. C 2022, 126 (36), 15386–15396. https://doi.org/10.1021/acs.jpcc.2c02489.
  17. Shehab, M. K.; Weeraratne, K. S.; Huang, T.; Lao, K. U.; El-Kaderi, H. M. Exceptional Sodium-Ion Storage by an Aza-Covalent Organic Framework for High Energy and Power Density Sodium-Ion Batteries. ACS Appl. Mater. Interfaces 2021, 13 (13), 15083–15091. https://doi.org/10.1021/acsami.0c20915.
  18. Spera, D.; Pate, D.; Spence, G. C.; Villot, C.; Onukwughara, C. J.; White, D.; Lao, K. U.; Özgür, Ü.; Arachchige, I. U. Colloidal Synthesis of Homogeneous Ge 1– x – y Si y Sn x Nanoalloys with Composition-Tunable Visible to Near-IR Optical Properties. Chem. Mater. 2023, 35 (21), 9007–9018. https://doi.org/10.1021/acs.chemmater.3c01644.
  19. Word, M. D.; López Peña, H. A.; Ampadu Boateng, D.; McPherson, S. L.; Gutsev, G. L.; Gutsev, L. G.; Lao, K. U.; Tibbetts, K. M. Ultrafast Dynamics of Nitro–Nitrite Rearrangement and Dissociation in Nitromethane Cation. J. Phys. Chem. A 2022, 126 (6), 879–888. https://doi.org/10.1021/acs.jpca.1c10288.
  20. Nobel Prize Outreach. The 1998 Nobel Prize in Chemistry. https://www.nobelprize.org/prizes/chemistry/1998/press-release/ (accessed 2024-09-23).
  21. The Nobel Prize in Chemistry 2013. NobelPrize.org. https://www.nobelprize.org/prizes/chemistry/2013/press-release/ (accessed 2024-09-23).

AXE Research SeminarSeptember 20, 2024 ▼

From Antihistamine to Anti-Infective: Loratadine Combats Methicillin-Resistant Staphylococcus aureus by Modulating Virulence, Antibiotic Resistance, and Biofilm Genes
- Professor Heather B. MillerOctober 11, 2024 ▼

  1. Cutrona, N.; Gillard, K.; Ulrich, R.; Seemann, M.; Miller, H. B.; Blackledge, M. S. From Antihistamine to Anti-Infective: Loratadine Inhibition of Regulatory PASTA Kinases in Staphylococci Reduces Biofilm Formation and Potentiates β-Lactam Antibiotics and Vancomycin in Resistant Strains of Staphylococcus Aureus. ACS Infect. Dis. 2019, 5 (8), 1397–1410. https://doi.org/10.1021/acsinfecdis.9b00096. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2232099104.
  2. Viering, B. L.; Balogh, H.; Cox, C. F.; Kirpekar, O. K.; Akers, A. L.; Federico, V. A.; Valenzano, G. Z.; Stempel, R.; Pickett, H. L.; Lundin, P. M.; Blackledge, M. S.; Miller, H. B. Loratadine Combats Methicillin-Resistant Staphylococcus Aureus by Modulating Virulence, Antibiotic Resistance, and Biofilm Genes. ACS Infect. Dis. 2024, 10 (1), 232–250. https://doi.org/10.1021/acsinfecdis.3c00616. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_10788911.

The Effect of Bicyclic Chalcogen-Phosphorus Rings on the Bergman Cyclization
- Marcos Hendler (student speaker)October 18, 2024 ▼

Optimizing the catalytic efficiency of cerium(IV) in cyclic di-GMP hydrolysis with ligands
- Raechel Parent (student speaker)October 18, 2024 ▼

25 Years Underground. Selected Chemical Adventures From My Time At Duke
- Dr. David GoodenNovember 1, 2024 ▼

  1. Carlson, D. L.; Kowalewski, M.; Bodoor, K.; Lietzan, A. D.; Hughes, P. F.; Gooden, D.; Loiselle, D. R.; Alcorta, D.; Dingman, Z.; Mueller, E. A.; Irnov, I.; Modla, S.; Chaya, T.; Caplan, J.; Embers, M.; Miller, J. C.; Jacobs-Wagner, C.; Redinbo, M. R.; Spector, N.; Haystead, T. A. J. Targeting Borrelia Burgdorferi HtpG with a Berserker Molecule, a Strategy for Anti-Microbial Development. Cell Chemical Biology 2024, 31 (3), 465-476.e12. https://doi.org/10.1016/j.chembiol.2023.10.004. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1016_j_chembiol_2023_10_004.
  2. Zhao, J.; Cochrane, C. S.; Najeeb, J.; Gooden, D.; Sciandra, C.; Fan, P.; Lemaitre, N.; Newns, K.; Nicholas, R. A.; Guan, Z.; Thaden, J. T.; Fowler, V. G.; Spasojevic, I.; Sebbane, F.; Toone, E. J.; Duncan, C.; Gammans, R.; Zhou, P. Preclinical Safety and Efficacy Characterization of an LpxC Inhibitor against Gram-Negative Pathogens. Sci. Transl. Med. 2023, 15 (708), eadf5668. https://doi.org/10.1126/scitranslmed.adf5668.

  1. Gooden, D. M.; Schmidt, D. M. Z.; Pollock, J. A.; Kabadi, A. M.; McCafferty, D. G. Facile Synthesis of Substituted Trans-2-Arylcyclopropylamine Inhibitors of the Human Histone Demethylase LSD1 and Monoamine Oxidases A and B. Bioorganic & Medicinal Chemistry Letters 2008, 18 (10), 3047–3051. https://doi.org/10.1016/j.bmcl.2008.01.003.
  2. Christensen, T.; Gooden, D. M.; Kung, J. E.; Toone, E. J. Additivity and the Physical Basis of Multivalency Effects:  A Thermodynamic Investigation of the Calcium EDTA Interaction. J. Am. Chem. Soc. 2003, 125 (24), 7357–7366. https://doi.org/10.1021/ja021240c.
  3. Gooden, D. M.; Chakrapani, H.; Toone, E. J. C-Nitroso Compounds: Synthesis, Physicochemical Properties and Biological Activities. Current Topics in Medicinal Chemistry 2005, 5 (7), 687–705. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_68480304. 
  4. Gooden, D. Facility Overview. Duke Small Molecule Synthesis Facility. https://sites.duke.edu/smsf/facility-overview/ (accessed 2024-11-07).
  5. Gooden, D. M. Synthesis and Physical Organic Chemistry of C-Nitroso Compounds: A Study of C-Nitroso Ketones as Selective Nitrosonium Donors. Ph.D., Duke University, United States -- North Carolina, 2006. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_journals_305327542 (accessed 2024-11-07).

Dr. Michelle BrannNovember 7, 2024 ▼

  1. Brann, M. R.; Hansknecht, S. P.; Muir, M.; Sibener, S. J. Acetone–Water Interactions in Crystalline and Amorphous Ice Environments. J. Phys. Chem. A 2022, 126 (17), 2729–2738. https://doi.org/10.1021/acs.jpca.2c01437.
  2. Brann, M. Condensed Phase Adsorption and Reactivity: Extraterrestrial Ices, Isotopic Enrichment, Olefin Oxidation, and Nerve Agent Simulants. Ph.D., The University of Chicago, United States -- Illinois, 2022. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_journals_2718700836 (accessed 2024-11-11).
  3. Brann, M. R.; Ma, X.; Sibener, S. J. Isotopic Enrichment Resulting from Differential Condensation of Methane Isotopologues Involving Non-Equilibrium Gas–Surface Collisions Modeled with Molecular Dynamics Simulations. J. Phys. Chem. C 2023, 127 (27), 13286–13294. https://doi.org/10.1021/acs.jpcc.3c02386.
  4. Balucani, N.; Bertin, M.; Brann, M.; Brown, W. A.; Ceccarelli, C.; Martín-Doménech, R.; Fulker, J.; Garrod, R. T.; Green, J.; Gudipati, M. S.; Heard, D. E.; Herbst, E.; Jacovella, U.; Kamp, I.; McCoustra, M. R. S.; Sameera, W. M. C.; Sims, I.; Sturm, A.; Viti, S.; Weaver, S. W.; Wiesenfeld, L.; Wilkins, O. H. Laboratory Astrochemistry of and on Dust and Ices: General Discussion. Faraday Discuss. 2023, 245 (0), 519–540. https://doi.org/10.1039/D3FD90026F.
  5. Williams, D. A.; Cecchi-Pestellini, C. Astrochemistry: Chemistry in Interstellar and Circumstellar Space; Royal Society of Chemistry: Cambridge, UK, 2023. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/191gg5k/alma9928397010806241. 
  6. Balucani, N.; Brann, M.; Brünken, S.; Ceccarelli, C.; Cordiner, M.; Crump, E. M.; Douglas, K. M.; Fleisher, A. J.; Flint, A.; Fulker, J.; Garrod, R. T.; Gudipati, M. S.; Gupta, D.; Halpern, J.; Heard, D. E.; Herbst, E.; Hockey, E. K.; Huang, K.-Y.; Jacovella, U.; Kamp, I.; Lemmens, A. K.; Madhusudhan, N.; McCoustra, M. R. S.; McGuire, B.; Meijer, A.; Puzzarini, C.; Rap, D. B.; Sims, I. R.; Stockett, M. H.; Sturm, A.; Suits, A. G.; Dishoeck, E. F. van; Viti, S.; Walker, N.; Weaver, S. W.; Wiesenfeld, L.; Wilkins, O. H. Laboratory Astrochemistry of the Gas Phase: General Discussion. Faraday Discuss. 2023, 245 (0), 391–445. https://doi.org/10.1039/D3FD90025H.

Dr. Jason CalvinNovember 12, 2024 ▼

  1. Barmparis, G. D.; Lodziana, Z.; Lopez, N.; Remediakis, I. N. Nanoparticle Shapes by Using Wulff Constructions and First-Principles Calculations. Beilstein J. Nanotechnol. 2015, 6 (1), 361–368. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_doaj_primary_oai_doaj_org_article_516da62f43d44ffdad247ea1fd462a87.
  2. Brewer, A. S.; Calvin, J. J.; Alivisatos, A. P. Impact of Uniform Facets on the Thermodynamics of Ligand Exchanges on Colloidal Quantum Dots. J. Phys. Chem. C 2023, 127 (21), 10270–10281. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1021_acs_jpcc_3c00187.
  3. Calvin, J. J. Organic Ligands and Colloidal Nanocrystal Surface Thermodynamics. Ph.D., University of California, Berkeley, California, USA, 2022. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_journals_3111066737.
  4. Calvin, J. J.; Brewer, A. S.; Crook, M. F.; Kaufman, T. M.; Alivisatos, A. P. Observation of Negative Surface and Interface Energies of Quantum Dots. Proceedings of the National Academy of Sciences 2024, 121 (18). https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_unpaywall_primary_10_1073_pnas_2307633121.
  5. Calvin, J. J.; Kaufman, T. M.; Sedlak, A. B.; Crook, M. F.; Alivisatos, A. P. Observation of Ordered Organic Capping Ligands on Semiconducting Quantum Dots via Powder X-Ray Diffraction. Nat Commun 2021, 12 (1), 2663. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_doaj_primary_oai_doaj_org_article_6a70a0dab9604fc9b2b18bc6c4f012be.
  6. Calvin, J. J.; O’Brien, E. A.; Sedlak, A. B.; Balan, A. D.; Alivisatos, A. P. Thermodynamics of Composition Dependent Ligand Exchange on the Surfaces of Colloidal Indium Phosphide Quantum Dots. ACS Nano 2021, 15 (1), 1407–1420. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2475528117.
  7. Calvin, J. J.; Sedlak, A. B.; Brewer, A. S.; Kaufman, T. M.; Alivisatos, A. P. Evidence and Structural Insights into a Ligand-Mediated Phase Transition in the Solvated Ligand Shell of Quantum Dots. ACS Nano 2024, 18 (36), 25257–25270. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_3097492829.
  8. Calvin, J. J.; Swabeck, J. K.; Sedlak, A. B.; Kim, Y.; Jang, E.; Alivisatos, A. P. Thermodynamic Investigation of Increased Luminescence in Indium Phosphide Quantum Dots by Treatment with Metal Halide Salts. J. Am. Chem. Soc. 2020, 142 (44), 18897–18906. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2454124135.
  9. Geyer, S. M.; Scherer, J. M.; Jaworski, F. B.; Bawendi, M. G. Multispectral Imaging via Luminescent Down-Shifting with Colloidal Quantum Dots. Opt. Mater. Express, OME 2013, 3 (8), 1167–1175. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_unpaywall_primary_10_1364_ome_3_001167.
  10. Kagan, C. R.; Bassett, L. C.; Murray, C. B.; Thompson, S. M. Colloidal Quantum Dots as Platforms for Quantum Information Science. Chem. Rev. 2021, 121 (5), 3186–3233. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2473752687.
  11. Levchenko, A. A.; Li, G.; Boerio-Goates, J.; Woodfield, B. F.; Navrotsky, A. TiO2 Stability Landscape:  Polymorphism, Surface Energy, and Bound Water Energetics. Chem. Mater. 2006, 18 (26), 6324–6332. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_istex_primary_ark_67375_TPS_XMNMF8GK_4.
  12. Nanoparticle Technology Handbook, 3rd edition.; Makio Naito, Toyokazu Yokoyama, Kouhei Hosokawa, Kiyoshi Nogi, Eds.; Elsevier: Amsterdam, 2018. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/191gg5k/alma9928388335006241. 
  13. O’Brien, E. A. Driving Forces and Effects of Ligand Exchange in Nanocrystalline Systems. Ph.D., University of California, Berkeley, United States -- California, 2018. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_journals_2507722249 (accessed 2024-11-18).
  14. Oh, M. H.; Cho, M. G.; Chung, D. Y.; Park, I.; Kwon, Y. P.; Ophus, C.; Kim, D.; Kim, M. G.; Jeong, B.; Gu, X. W.; Jo, J.; Yoo, J. M.; Hong, J.; McMains, S.; Kang, K.; Sung, Y.; Alivisatos, A. P.; Hyeon, T. Design and Synthesis of Multigrain Nanocrystals via Geometric Misfit Strain. Nature 2020, 577 (7790), 359-363,363A. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_unpaywall_primary_10_1038_s41586_019_1899_3.
  15. Talapin, D. V.; Mekis, I.; Götzinger, S.; Kornowski, A.; Benson, O.; Weller, H. CdSe/CdS/ZnS and CdSe/ZnSe/ZnS Core−Shell−Shell Nanocrystals. J. Phys. Chem. B 2004, 108 (49), 18826–18831. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1021_jp046481g.
  16. Utzat, H.; Sun, W.; Kaplan, A. E. K.; Krieg, F.; Ginterseder, M.; Spokoyny, B.; Klein, N. D.; Shulenberger, K. E.; Perkinson, C. F.; Kovalenko, M. V.; Bawendi, M. G. Coherent Single-Photon Emission from Colloidal Lead Halide Perovskite Quantum Dots. Science 2019, 363 (6431), 1068–1072. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_unpaywall_primary_10_1126_science_aau7392.
  17. Werz, T.; Baumann, M.; Wolfram, U.; Krill, C. E. Particle Tracking during Ostwald Ripening Using Time-Resolved Laboratory X-Ray Microtomography. Materials Characterization 2014, 90, 185–195. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_osti_scitechconnect_22340354.
  18. Xu, F.; Zhou, W.; Navrotsky, A. Cadmium Selenide: Surface and Nanoparticle Energetics. Journal of Materials Research 2011, 26 (5), 720–725. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_1671563007.
  19. Zherebetskyy, D.; Scheele, M.; Zhang, Y.; Bronstein, N.; Thompson, C.; Britt, D.; Salmeron, M.; Alivisatos, P.; Wang, L.-W. Hydroxylation of the Surface of PbS Nanocrystals Passivated with Oleic Acid. Science 2014, 344 (6190), 1380–1384. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_jndl_porta_oai_ndlsearch_ndl_go_jp_R100000136_I1363107369952846336.
  20. Zrazhevskiy, P.; Sena, M.; Gao, X. Designing Multifunctional Quantum Dots for Bioimaging, Detection, and Drug Delivery. Chem. Soc. Rev. 2010, 39 (11), 4326–4354. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3212036.

Dr. J.J. JiangNovember 14, 2024 ▼

  1. Borsovszky, J.; Nauta, K.; Jiang, J.; Hansen, C. S.; McKemmish, L. K.; Field, R. W.; Stanton, J. F.; Kable, S. H.; Schmidt, T. W. Photodissociation of Dicarbon: How Nature Breaks an Unusual Multiple Bond. Proceedings of the National Academy of Sciences 2021, 118 (52), e2113315118. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_8719853.
  2. Jiang, J. Diabatic Valence-Hole Concept. J. Phys. Chem. A 2024, 128 (17), 3253–3265. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_osti_scitechconnect_2427464.
  3. Jiang, J.; McCartt, A. D. Two-Color, Intracavity Pump–Probe, Cavity Ringdown Spectroscopy. The Journal of Chemical Physics 2021, 155 (10), 104201. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_journals_2570212368.
  4. Jiang, J.; McCartt, A. D. Mid-Infrared Trace Detection with Parts-per-Quadrillion Quantitation Accuracy: Expanding Frontiers of Radiocarbon Sensing. Proceedings of the National Academy of Sciences 2024, 121 (15), e2314441121. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_osti_scitechconnect_2326247.
  5. Jiang, J.; Ye, H.-Z.; Nauta, K.; Van Voorhis, T.; Schmidt, T. W.; Field, R. W. Diabatic Valence-Hole States in the C2 Molecule: “Putting Humpty Dumpty Together Again.” J. Phys. Chem. A 2022, 126 (20), 3090–3100. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_osti_scitechconnect_1877979.
  6. McCartt, A. D.; Jiang, J. Room-Temperature Optical Detection of 14CO2 below the Natural Abundance with Two-Color Cavity Ring-Down Spectroscopy. ACS Sens. 2022, 7 (11), 3258–3264. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_osti_scitechconnect_2263528.

Dr. Collin SteenNovember 19, 2024 ▼

  1. Demmig-Adams, B.; Stewart, J. J.; López-Pozo, M.; Polutchko, S. K.; Adams, W. W. Zeaxanthin, a Molecule for Photoprotection in Many Different Environments. Molecules 2020, 25 (24), 5825. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_doaj_primary_oai_doaj_org_article_6225cf259267455e8a29c52095f2a388.
  2. Erickson, E.; Wakao, S.; Niyogi, K. K. Light Stress and Photoprotection in Chlamydomonas Reinhardtii. The Plant Journal 2015, 82 (3), 449–465. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_osti_scitechconnect_1400706.
  3. Głowacka, K.; Kromdijk, J.; Kucera, K.; Xie, J.; Cavanagh, A. P.; Leonelli, L.; Leakey, A. D. B.; Ort, D. R.; Niyogi, K. K.; Long, S. P. Photosystem II Subunit S Overexpression Increases the Efficiency of Water Use in a Field-Grown Crop. Nat Commun 2018, 9 (1), 868. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_doaj_primary_oai_doaj_org_article_abfd5de63c3e4800a4a2059d0f38c8c9.
  4. Hubbart, S.; Smillie, I. R. A.; Heatley, M.; Swarup, R.; Foo, C. C.; Zhao, L.; Murchie, E. H. Enhanced Thylakoid Photoprotection Can Increase Yield and Canopy Radiation Use Efficiency in Rice. Commun Biol 2018, 1 (1), 1–12. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6123638.
  5. Kromdijk, J.; Głowacka, K.; Leonelli, L.; Gabilly, S. T.; Iwai, M.; Niyogi, K. K.; Long, S. P. Improving Photosynthesis and Crop Productivity by Accelerating Recovery from Photoprotection. Science 2016, 354 (6314), 857–861. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_osti_scitechconnect_1832459.
  6. Litvín, R.; Bína, D.; Herbstová, M.; Gardian, Z. Architecture of the Light-Harvesting Apparatus of the Eustigmatophyte Alga Nannochloropsis Oceanica. Photosynth Res 2016, 130 (1), 137–150. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_1837325827.
  7. Mennicke, U.; Salditt, T. Preparation of Solid-Supported Lipid Bilayers by Spin-Coating. Langmuir 2002, 18 (21), 8172–8177. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_crossref_primary_10_1021_la025863f.
  8. Müller, P.; Li, X.-P.; Niyogi, K. K. Non-Photochemical Quenching. A Response to Excess Light Energy1. Plant Physiology 2001, 125 (4), 1558–1566. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_1539381.
  9. Park, S.; Steen, C. J.; Fischer, A. L.; Fleming, G. R. Snapshot Transient Absorption Spectroscopy: Toward in Vivo Investigations of Nonphotochemical Quenching Mechanisms. Photosynth Res 2019, 141 (3), 367–376. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_osti_scitechconnect_1656532.
  10. Park, S.; Steen, C. J.; Lyska, D.; Fischer, A. L.; Endelman, B.; Iwai, M.; Niyogi, K. K.; Fleming, G. R. Chlorophyll–Carotenoid Excitation Energy Transfer and Charge Transfer in Nannochloropsis Oceanica for the Regulation of Photosynthesis. Proceedings of the National Academy of Sciences 2019, 116 (9), 3385–3390. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_6397512.
  11. Ruban, A. V. Crops on the Fast Track for Light. Nature 2017, 541 (7635), 36–37. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_journals_1856850697.
  12. Short, A. H.; Fay, T. P.; Crisanto, T.; Hall, J.; Steen, C. J.; Niyogi, K. K.; Limmer, D. T.; Fleming, G. R. Xanthophyll-Cycle Based Model of the Rapid Photoprotection of Nannochloropsis in Response to Regular and Irregular Light/Dark Sequences. The Journal of Chemical Physics 2022, 156 (20), 205102. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_scitation_primary_10_1063_5_0089335.
  13. Steen, C. J.; Burlacot, A.; Short, A. H.; Niyogi, K. K.; Fleming, G. R. Interplay between LHCSR Proteins and State Transitions Governs the NPQ Response in Chlamydomonas during Light Fluctuations. Plant, Cell & Environment 2022, 45 (8), 2428–2445. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_osti_scitechconnect_1873421.
  14. Steen, C. J.; Morris, J. M.; Short, A. H.; Niyogi, K. K.; Fleming, G. R. Complex Roles of PsbS and Xanthophylls in the Regulation of Nonphotochemical Quenching in Arabidopsis Thaliana under Fluctuating Light. J. Phys. Chem. B 2020, 124 (46), 10311–10325. https://richmond.primo.exlibrisgroup.com/permalink/01URICH_INST/10lhjt5/cdi_proquest_miscellaneous_2459355954.